WHMIS (Manganese methylcyclopentadienyl tricarbonyl)

Workplace Hazardous Materials Information System

WHMIS 2015 classification - Note to reader

• Acute toxicity - oral - Category 21 2 3 4 5 6 7

• Acute toxicity - dermal - Category 21 2 3 4 6 7 8

• Acute toxicity - inhalation - Category 11 2 3 4 6 7 8

• Specific target organ toxicity - repeated exposure - Category 11 3 4 7 9

Danger

Fatal if swallowed (H300)
Fatal in contact with skin (H310)
Fatal if inhaled (H330)
Causes damage to organs through prolonged or repeated exposure (H372)

Ingredient disclosure

References

• ▲1.  American Conference of Governmental Industrial Hygienists, Documentation of the threshold limit values and biological exposure indices / Documentation of TLV's and BEI's. 7th ed. Cincinnati, Ohio : ACGIH. (2001-). Publication #0100Doc. [RM-514008]   http://www.acgih.org
• ▲2.  National Institute for Occupational Safety and Health, RTECS (Registry of Toxic Effects of Chemical Substances). Hamilton (Ont) : Canadian Centre for Occupational Health and Safety.   http://ccinfoweb.ccohs.ca/rtecs/search.html
• ▲3.  Centre canadien d'hygiène et de sécurité au travail, CHEMINFO, Hamilton, Ont. : Canadian Centre for Occupational Health and Safety   http://ccinfoweb.ccohs.ca/cheminfo/search.html
• ▲4.  Bingham, E., Cohrssen, B. et Powell, C.H., Patty's toxicology. A Wiley-Interscience publication, 5ème éd. New York (NY) : John Wiley & Sons. (2001). [RM-214008]
• ▲5.  Hysell, D.K. et al., «Oral toxicity of methylcyclopentadienyl manganese tricarbonyl in rats.» Environmental Research. Vol. 7, p. 158-168. (1974). [AP-062534]
• ▲6.  Lewis, RJ., Sax's dangerous properties of industrial materials : H-Z. Vol. 3, 9ème éd. New York : Van Nostrand Reinhold. (1996).
• ▲7.  IFA-Gestis, Information system on hazardous substances of the German Social Accident Insurance. Sankt Augustin, Germany : Institut für Arbeitsschutz der Deutschen Gesetzlichen Unfallversicherung (IFA).   https://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
• ▲8.  Hinderer, R.K., «Toxicity studies of methylcyclopentadienyl manganese tricarbonyl (MMT).» American Industrial Hygiene Association Journal. Vol. 40, p. 164-167. (1979).
• ▲9.  International Programme on Chemical Safety, Methylcyclopentadienyl manganese tricarbonyl. ICSC #1169. IPCS, CEC. (2003).   http://www.inchem.org/documents/icsc/icsc/eics1169.htm
  http://www.inchem.org/

The [number] refers to the Information SST database of the CNESST Documentation Center.