WHMIS (Phenyllithium)

Workplace Hazardous Materials Information System

WHMIS 2015 classification - Note to reader

• Pyrophoric solids - Category 11 2

• Skin corrosion/irritation - Category 1

• Serious eye damage/eye irritation - Category 1

• Specific target organ toxicity - single exposure (respiratory tract irritation) - Category 3 - Respiratory tract irritation

• Physical hazards not otherwise classified (exclamation mark) - Category 12 3 4

Danger

Catches spontaneously if exposed to air (H250)
Causes severe skin burns and eye damage (H314)
May cause respiratory irritation (H335)
Reacts violently or explosively in contact with water at ambient temperature

Ingredient disclosure

Comments2 3 4 : There are no data available for phenyllithium regarding its irritation or corrosion ability. However, it forms on contact with water a corrosive substance: lithium hydroxide.

References

• ▲1.  Kroschwitz, J.I., Kirk-Othmer encyclopedia of chemical technology. 5th ed. Hoboken, N.J. : John Wiley & Sons. (2004-). [RT-423004]
• ▲2.  Lewis, RJ., Sax's dangerous properties of industrial materials : H-Z. Vol. 3, 9ème éd. New York : Van Nostrand Reinhold. (1996).
• ▲3.  Vollhardt, K.P.C., Traité de chimie organique. Montréal : Éditions du Renouveau Pédagogique. (1990). [MO-014510]
• ▲4.  Bohnet, M. et al., Ullmann's Encyclopedia of Industrial Chemistry. 7th. Wiley InterScience (John Wiley & Sons). (2003-).   http://www3.interscience.wiley.com (http://www3.interscience.wiley.com/cgi-bin/mrwhome/104554801/HOME)

The [number] refers to the Information SST database of the CNESST Documentation Center.